One of the most important phenomena of some systems is chaos which is caused by nonlinear dynamics. In this paper, the new 3 dimensional chaotic system is firstly investigated and then utilizing an intelligent controller which based on brain emotional learning (BELBIC), this new chaotic system is synchronized. The BELBIC consists of reward signal which accept positive values. Improper selection of the parameters causes an improper behavior which may cause serious problems such as instability of system. It is needed to optimize these parameters. Genetic Algorithm (GA), Cuckoo Optimization Algorithm (COA), Particle Swarm Optimization Algorithm (PSO) and Imperialist Competitive Algorithm (ICA) are used to compute the optimal parameters for the reward signal of BELBIC. These algorithms can select appropriate and optimal values for the parameters. These minimize the Cost Function, so the optimal values for the parameters will be founded. Selected cost function is defined to minimizing the least square errors. Cost function enforce the system errors to decay to zero rapidly. Numerical simulation results are presented to show the effectiveness of the proposed method.